is nitrate, the same across the board? I mean is the the nitrate we find as a result of the nitrification process in aquariums from fish excretion and respiration etc, breakdown of food matter and (if planted) plant matter, exactly the same as the nitrates we find in our tap water?
As far as I know, yes. "Nitrate" in water is nitrate, NO3-, which the US Dept of Agriculture defines thus: "Nitrates and nitrites are nitrogen-oxygen chemical units which combine with various organic and inorganic compounds."
I wonder, as from what I have read the nitrate in tap water usually occurs as the naturally occurring water drains through agricultural land picking up as it filters through the ground decaying plant matter, then goes onto the underground reservoirs which are tapped by the water companies. Am I also right in thinking that this is how water picks up its hardness, when filtering through areas high in minerals?
Water is one of the most powerful solvents on earth. "Solvent" means a substance that easily dissolves other substances to create a solution. Water thus takes up organics, minerals, etc. very readily as it comes into contact with these substances.
So my question, how is high nitrate levels actually detrimental to fish? and is it just the decaying plant matter that is the problem? or is nitrate just a chemical produced by the decaying matter, and the decaying matter is not actually present physically? This is where I am confused, and would like clarification.
Nitrate is one form of nitrogen, as are ammonia/ammonium, nitrite and nitrogen gas. While nitrogen is essential to life as we know it on the face of the earth--nitrogen forms about 80% of the earth's atmosphere, and all life forms work hard to acquire it since it is essential for amino acids, proteins, DNA and RNA--it is also highly toxic depending upon the form in which it occurs. The diagram below shows the nitrogen cycle.
Organisms have a tendency to convert some nitrate back into nitrite which as we know is very highly toxic at a very small level. High levels of nitrate, above 40 ppm, have been shown to slow fish growth, suppress breeding, and depress the immune system making the fish much more susceptible to disease. Just as in humans where nitrates in drinking water most affect babies, in fish the fry are even more seriously harmed by nitrates. All of our fish occur in waters with nitrate so low it can scarcely be measured.
Here is some data pulled from an article on nitrates at OscarFish.com:
Kincheloe et al. (1979) reported larval mortality of Chinook salmon, rainbow trout, and cutthroat trout at concentrations as low as 2.3-7.6 mg/L NO3-N. That's equal to 2 to 7 ppm. We tend to think of keeping nitrate below 20ppm...quite a difference. Different fish species have varying levels of tolerance to nitrate. A recent study which reviewed all prior studies on the impacts of nitrates suggests that the most sensitive freshwater invertebrates and fish are affected by nitrate concentration as low as 2ppm, with the primary physiological impact being a decreased ability of the blood to carry oxygen (anemia).
A study on the effect of nitrates on fish found these effects:
- Affects antibody production
- Increased number of immature red blood cells
- Lowered level of mature red blood cells (anemia)
- Higher count of monocyte (a specific white blood cell)
- Higher count of neutrophil (a specific white blood cell that is especially destructive to microorganisms)
- Higher count of TLC - Thrombocyte-like cell (a blood cell of nonmammalian vertebrates that promotes blood clotting)
- Higher levels of creatine (A nitrogenous organic acid found in muscle tissue that supplies energy for muscle contraction)
- Higher calcium values in the blood
- Lower Chloride values in the blood
- Autopsy revealed damage to the spleen, liver, and kidneys
Also, nitrate damaged the gills and kidneys affecting osmoregulatory ability (ability of the fish to regulate fluid levels and release toxins, something we do via urination, something they do via osmoregulation); these observed changes are the result of a pathological response and not of a generalized stress response.
are the two, nitrates present as part of the natural nitrification cycle in aquariums and tap water nitrates, that have come from a water treatment plant the same?
As far as I understand, yes.
I also have around 40ppm nitrate right out of my tap, I just add it to my tank, it doesn't seem to bother the fish, although I know its a long haul problem, affecting the natural life span of the fish, I struggle to see how this is so bad for the fish?
The above answers the "how." I believe in the USA that 40ppm is the upper limit allowed for nitrates due to the effect on humans, esp children.