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Regarding your nitrates, several water changes for the next few days should help.

A protein skimmer in a freshwater tank is useless since there is not enough proteing buildup in a freshwater tank.

Just curious...Have you tested or tap water if there are any nitrates?

What kind of filter do you use?

How much do you feed your fish? How many times?

What kind of fish do you have in the tank?
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