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Just a word of caution about keeping angelfish, gourami, and neons & guppies in a 45 gallon tank... long term this is not likely to work, regardless of the plants you add. Angelfish and gourami will get too large to keep together in this size of a tank, and once large enough, they will likely eat neons and guppies. Watch growth rate, water params (which the plants will help to keep stable) and aggression levels. To help keep the peace between angel and gourami for a little longer, I'd also add some type of floating plant to your list, such as hornwort. This will help with your "jungle appearance" and create extra territory for the 2 fish occupying the upper 1/2 of the tank.
Good Luck and bring us more pics as you make your progress.
 
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