I just came to this thread, but I have a couple of comments. First, the vinegar test. It is not totally accurate/reliable; the household vinegar is too weak of an acid [after all, we do eat/drink it on foods] to be a certainty. A better acid to use is the Regent #2 in the API nitrate test, as it is stronger. But, if vinegar does fizz, it would mean that the substance is calcareous.
The paver sand is as AbbeysDad clearly stated, so avoid it. Obviously it is calcareous, plus the binding issue.
Mixing different substrates usually does not work. It "looks" artificial. Especially when dark colours like black or brown are mixed with anything.
I have Quikrete [or however it is spelt] playsand in my 115g, 33g and 10g now. It is inert, and although it is not as dark underwater as it is in air, it is still neutral. I reduce my lighting anyway, and have floating plants, and a lot of wood, rock, substrate plants--all of which help. It is almost identical to the sand in many Amazonian streams, particularly the Rio Negro basin. So for most corys it is like "home." I am truly pleased with the results.
Byron.