I applaud you for doing some research before you stock your tank!!! That is really commendable!!!
BUT... I hate to be the bearer of bad news, but... There are some problems here. Some more research is needed. You can click on the shaded species names for more information.
In the fist set up, the Rainbow Shark will become aggressive towards the other bottom dwellers, especially the Corydoras. The Clown Loach will become too big for you tank. And if you have 2 Pearl Gourami, they should be a mated pair. You could do this set up without the Rainbow Shark and Clown Loach, but you should research how the Pearl Gourami and Silver Hatchetfish will get along.
In the second set up, there's a good chance that as soon as the Pictus Catfish and Scalare Angelfish get big enough, they'll eat the Neon Tetra. The Boeseman Rainbowfish and Pictus Catfish will be too active for the sedate Scalare Angelfish. The Scalare Angelfish should be kept in either a breeding pair (which would not work with the other fish), or in a group of 5 or more (which wouldn't give you room for the other fish). The Gernan Blue Ram (electric blue color variation) need temperatures that are too high for the other fish.
If you give us your favorite fish that you'd def like to keep, and your water parameters (pH, hardness, Ammonia, Nitrite, Nitrate, tank dimensions, etc), then we can build a tank around them.